Synthesis, Structure, and Reactivity of Rare-Earth Metallocene η3-Propargyl/Allenyl Complexes
نویسندگان
چکیده
منابع مشابه
A bipyridyl thorium metallocene: synthesis, structure and reactivity.
The synthesis, structure and reactivity of a new bipy thorium metallocene have been studied. The reduction of the thorium chloride metallocene [η(5)-1,3-(Me(3)C)(2)C(5)H(3)](2)ThCl(2) (1) with potassium graphite in the presence of 2,2'-bipyridine gives the purple bipy metallocene [η(5)-1,3-(Me(3)C)(2)C(5)H(3)](2)Th(bipy) (2) in good yield. Complex 2 has been fully characterized by various spect...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2008
ISSN: 0276-7333,1520-6041
DOI: 10.1021/om800547n